This week, I've rounded up three examples of "molecules" - one real, two not-so-real - from the world outside the lab.
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| Source: Wellcome trust |
Amino Acid - I watched a YouTube
clip of Guardian
Neurophilosophy blogger Mo Costandi explaining to the Wellcome trust about why he blogs (
Fun Fact: Mo worked as a security guard prior to becoming a science writer). At the end of the video,
Wellcome displays a splash card with a mission statement and a ball-and-stick model: hey, it's L-serine! It's always nice to see a correctly-drawn molecule in advertising, especially when they could have picked a neuron, a cell, or a goofy
staged picture instead (
Watch, as science blogger adds droplets to bright red solution!!!).
Of course, my science
spider-sense needs to clarify two very minor points. First: at neutral pH, solitary amino acids usually like to exist as
zwitterions, which would mean that the nitrogen (blue) picks up a proton, and the carboxylic acid (red) loses one (COO-). Two: since we're discussing neurology here, I can't help but feel that they might have meant to show neurotransmitter
D-serine, the
enantiomer (mirror image). Turns out, the body generates D-serine from L-serine in the brain using a specific enzyme, serine
racemase.
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| Found: hanging on the Shell station door |
Nitrogen Enhanced Gas - Last month, Shell Oil company released a new generation of its detergent-containing gasoline, designed to protect your engine from "
performance-robbing gunk," or carbon deposit buildup on intake valves. Look at their new logo*, pasted all over the station's pumps, doors, and road signs: what the heck is that
blue thing? Counting quickly, I'd assume that it's nonane, the 9-carbon cousin of octane, the main component of gasoline. Well, that can't be it, because that doesn't have any nitrogen! Writer Michael McCoy came up against the same such pseudo-scientific "ziggy-zaggy molecule" in his
C&EN article (
Chem. Eng. News 2009,
87(14), 20-21).
Digging briefly through the patent lit, I came across US7,901,470B2 (
2011), titled simply "Gasoline Additives," and co-written by six Shell Oil engineers. A sampling:
"a hydrocarbyl amine...in the range 155 to 255 as an additive in unleaded gasoline...for reducing injector nozzle fouling..."
Looks like we're on the right track. Read a few more 'grafs down, and they mention...
dodecylamine. In fact, they say "
...found to be particularly effective," which in patent-speak means they should probably add a few more carbons and an amine group onto that sign! On a more serious note, there's a debate
brewing over whether such detergents help engines while harming the atmosphere, by producing extra NOx emissions.
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| Credit: ST:TNG | Paramount Pictures |
Star Trek Set Design - Watching through old episodes of
ST:TNG, a tiny detail caught my eye. In the 24th Century, young Wesley Crusher, the oft-misunderstood teen wunderkind, studies such subjects as nano-engineering, quantum physics, and...chemistry? Check out this screen shot from season 3, episode 1; it seems researchers in
Stardate 43125.8 are still using the old HGS
modeling kit (a personal favorite, btw).
And what structure do we have here? Judging by the color-code, normally, red = O, black = C, white = H, I'd guess a type of dual hyperoxygen**, an oxygen with four connected bonds
(oxygen usually likes two bonds, or 3, tops). I've heard of Olah's
hypercarbon, so maybe it's a take on that? Perhaps a form of matter we just haven't found yet? More likely, following the
example from
National Lampoon's Christmas Vacation, set designers simply aren't versed in synthesis.
Dear Hollywood - If you need to vet a structure or formula, do feel free to ask me. Operators with chalkboards and books are standing by!
*Editor's Note: Is that a registered trademark (R) symbol next to the word "nitrogen?" I wasn't aware that element names could be trademarked! Of course, I'll be immediately contacting the Just Like Cooking legal department to file for Argon(TM), Strontium(TM), Niobium(TM), and Roentgenium(TM). Y'all can fight over the rest.
**Bonus Round: Try putting "hyperoxygen" into Google. Mostly homeopathic cures, hyperbaric chambers, and folks who don't know what hydrogen peroxide really is.
And what structure do we have here? Judging by the color-code, normally, red = O, black = C, white = H, I'd guess a type of dual hyperoxygen**, an oxygen with four connected bonds (oxygen usually likes two bonds, or 3, tops). I've heard of Olah's hypercarbon, so maybe it's a take on that? Perhaps a form of matter we just haven't found yet? More likely, following the example from National Lampoon's Christmas Vacation, set designers simply aren't versed in synthesis.
