tag:blogger.com,1999:blog-6010505890506526002.post2398877362851627076..comments2024-03-28T07:04:52.697-04:00Comments on Just Like Cooking: Gold Steps UpSee Arr Ohhttp://www.blogger.com/profile/09464185815368499346noreply@blogger.comBlogger2125tag:blogger.com,1999:blog-6010505890506526002.post-70794637634268423932014-04-11T14:48:05.536-04:002014-04-11T14:48:05.536-04:00Lavallo and coworkers have an impressively active ...Lavallo and coworkers have an impressively active single component gold catalyst using a carborane.<br />http://onlinelibrary.wiley.com/doi/10.1002/anie.201209107/abstractAnonymousnoreply@blogger.comtag:blogger.com,1999:blog-6010505890506526002.post-50060444643132118472014-04-10T16:55:14.203-04:002014-04-10T16:55:14.203-04:00a word of caution: reactions that run with very lo...a word of caution: reactions that run with very low catalyst loadings either have to employ a robust catalyst, or they use highly optimized procedure and carefully purified starting materials. This kind of development work is better suited to process chemists. Especially if you have to form the catalyst in situ from a ligand and a metal source, with air sensitive precursors, it is a lot easier to perform it on large scale.<br /><br />milkshakehttps://www.blogger.com/profile/08188961610554710616noreply@blogger.com